Increase Allowed Maximum Message Size in Microsoft Exchange

Here are the CLI commands for default values (in case you need to reset them).

%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/Microsoft-Server-ActiveSync/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:30000000
%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/Microsoft-Server-ActiveSync/" -section:system.web/httpRuntime /maxRequestLength:10240
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/Microsoft-Server-ActiveSync/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:30000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/Microsoft-Server-ActiveSync/" -section:system.web/httpRuntime /maxRequestLength:10240
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/Microsoft-Server-ActiveSync/" -section:appSettings /[key='MaxDocumentDataSize'].value:10240000

%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/ews/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSAnonymousHttpsBinding'].httpsTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSAnonymousHttpBinding'].httpTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSBasicHttpsBinding'].httpsTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSBasicHttpBinding'].httpTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSNegotiateHttpsBinding'].httpsTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSNegotiateHttpBinding'].httpTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSWSSecurityHttpsBinding'].httpsTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSWSSecurityHttpBinding'].httpTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSWSSecuritySymmetricKeyHttpsBinding'].httpsTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSWSSecuritySymmetricKeyHttpBinding'].httpTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSWSSecurityX509CertHttpsBinding'].httpsTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /customBinding.[name='EWSWSSecurityX509CertHttpBinding'].httpTransport.maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /webHttpBinding.[name='EWSStreamingNegotiateHttpsBinding'].maxReceivedMessageSize:67108864
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/ews/" -section:system.serviceModel/bindings /webHttpBinding.[name='EWSStreamingNegotiateHttpBinding'].maxReceivedMessageSize:67108864

%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/owa/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:35000000
%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/owa/" -section:system.web/httpRuntime /maxRequestLength:35000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:35000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.web/httpRuntime /maxRequestLength:35000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpsBinding'].maxReceivedMessageSize:35000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpBinding'].maxReceivedMessageSize:35000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpsBinding'].readerQuotas.maxStringContentLength:35000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpBinding'].readerQuotas.maxStringContentLength:35000000

Here're the CLI commands to set message size to 100MB. We're updating both the ActiveSync and OWA channels.

%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/Microsoft-Server-ActiveSync/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:100000000
%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/Microsoft-Server-ActiveSync/" -section:system.web/httpRuntime /maxRequestLength:102400
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/Microsoft-Server-ActiveSync/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:100000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/Microsoft-Server-ActiveSync/" -section:system.web/httpRuntime /maxRequestLength:102400
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/Microsoft-Server-ActiveSync/" -section:appSettings /[key='MaxDocumentDataSize'].value:102400000

%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/owa/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:100000000
%windir%\system32\inetsrv\appcmd.exe set config "Default Web Site/owa/" -section:system.web/httpRuntime /maxRequestLength:100000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.webServer/security/requestFiltering /requestLimits.maxAllowedContentLength:100000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.web/httpRuntime /maxRequestLength:100000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpsBinding'].maxReceivedMessageSize:100000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpBinding'].maxReceivedMessageSize:100000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpsBinding'].readerQuotas.maxStringContentLength:100000000
%windir%\system32\inetsrv\appcmd.exe set config "Exchange Back End/owa/" -section:system.serviceModel/bindings /webHttpBinding.[name='httpBinding'].readerQuotas.maxStringContentLength:100000000